FWIW many pumps put out more GPM/LPM @ LOWER PSI ergo they would not sell/rate as such, IE Walbro & Delphi pumps rated 7psi & 45gph, and GM lift 28gph at same psi.
Back in my USN days multiple pumps on ships our fire pumps were 1750gpm rated @ 150 psi, seawater service pump 3000gpm @ 70 psi, physically smaller/larger pumps so yes you can have a difference of psi over gpm/gph and vice versa.
Now parallel vs series not sure one over the other makes a difference, with exception since GM pumps are self regulating my thoughts were that the 2 pumps would not be working as efficiently in series as they might be cycling off/on more than if they were in parallel with separate switches to secure them when not needed,.
Plus the outlet valve of the GM pumps if plumbed in series would both wear at same rate as both would have constant flow across the "innards" of the pumps.
My setup in parallel allows for redundancy in event 1 pump gets weak or inoperative I switch on the offline pump to take over, in series with both pumping both are on same duty cycle, in shipboard systems where I learned how systems are built pumps are often built with redundant parallel capability in mind.
As to flow vs psi with me opening for full FTB is have larger lines to be filled than the OEM set up so recovery when WOT or heavy load demand requires a larger gph pump capability, (2) 28 gph pumps in parallel by math is more than a single 45gph pump, but in series the flow restrictions internal to the pump themselves may negate some of total delivered volume.
With my setup (1) 45 gph parallel with a 28 gph neither pump impedes the flow of the other limit to the flow is how much fuel the IP is "gulping up", a single Raptor significantly more flow potential than my setup, but Raptor cost and all eggs in 1 basket /pump are not my desire.
Is my setup the best, maybe/maybe not but it works well for me since installing nearly 4 yeas ago.