What's the cost of this vs. buying a 6.5 Tahoe used? Emissions, you may not care, will limit your resale ability period.
The 6.2 and 6.5 have nearly the same bolt holes differing only in oil cooler line size. (I have swapped as far back as 1985 6.2's heads and all to 1993/1995 6.5 serp drive with all 6.5 bolts and brackets) Throw whatever belt drive you want on it making sure you get all the brackets - there is a setup for sale on
here (link) now. IMO the wide belts the 6.2 V belt drives used are not available anymore and new v-belts stretch out quick. (YUCK!!!)
The PS pump needs the proper diesel relief valve if there is even a difference. Variable assist if equipped needs to go out the window even if diesel equipped OEM due to being a PIA. Diesel tach's, if you are changing the cluster, require a larger alternator pulley.
Wiring harness, ECM, transmission, transmission control... Just getting the speedometer and cruise working will be fun. Air bag, ABS, etc, etc. More weight in the front mean you have to crank up the torsion bars - really have the wrong ones in there for the diesel weight so ride suffers as you are out of the sweet spot they were designed for weight wise.
Add a second battery and slow down the alternator appears dumb... IMO it's done because the diesel vibrations snap off alternator mounts and/or split alternators in half now. So slowing them down reduces the speed up slow down multiplied vibration from the engine on them. The faster you drive the alternator the more stress slowing down and speeding up has on it and it's mounts. Each compression and power stroke on a 21:1 compression diesel is an exciting slow down and explosion speed up at idle...