75W140,
First number is cold viscosity index.
Second number is hot viscosity index.
A synthetic in this weight will most likely cold flow better than Dino 75-weight oil will. But the real goodness is that it’ll only thin out at operating temps to what 140-weight dino oil would; in reality it has more to do with film strength and shear. (Caveat) this is a gross over simplification, a true definition can be found at the American Petroleum Institute
www.api.org.
Long story short, I don’t believe you would see any significant fuel mileage decrease running group 4-5 full Syn 75W140 vs. Dino 75W90. The positives far outweigh the negatives going Syn, with the exception of some pre-90’s axle seals that have non-Syn compatible rubber. I believe at this point almost all automotive Syn fluids have seal conditioners added, as group 4-5 Syn like PAO’s can suck seals dry (leaks)!
Please keep in mind that since the big Exxon/Mobile lawsuit, then ironic merger, that not all synthetics nowadays would have been classified as such previously. Now a hydrocracked petroleum molecule is classified as a synthetic. Top tier Synthetics are still group 4-5 esters, olefins, PAO, Etc, which may have been chemically engineered from petrol derived feed stock, but were far more complex to mfg than a highly refined/simple hydrocrack’ed distillation petrol product.